Hydrodehalogenation of hexachloro- and hexabromobenzene by metallic calcium in ethanol, in the presence of Rh/C catalyst
2017
Both
hexachlorobenzeneand
hexabromobenzenewere successfully hydrodehalogenated to the monohalogenated derivative and ultimately to benzene (which was subsequently reduced to
cyclohexane) using a mixture of metallic Ca, ethanol, and Rh/C, by simple stirring in
diethyl ether, at room or mild temperature (60 °C). Various experiments were performed in order to assess the role of the solvent and Rh/C catalyst, as well as for elucidating the reaction pathway.
Keywords:
-
Correction
-
Source
-
Cite
-
Save
38
References
3
Citations
NaN
KQI