THE U-Pb AGE AND Lu-Hf ISOTOPE SYSTEMATICS OF ZIRCON FROM THE HULIAIPOLE MET AVOLCANICS, THE AZOV DOMAIN OF THE UKRAINIAN SHIELD: EVIDENCE FOR THE PALEOARCHEAN-HADEAN CRUST

The Azov Domain occurs as a part of a larger Mesoarchean (3.2-3.0 Ga) craton, fragments of which are preserved in the eastern part of the Ukrainian Shield and as a block of the Kursk Magnetic Anomaly (KMA). In the Neoarchean-Palaeoproterozoic time, it was fragmented into several tectonic blocks: Vovcha, Remivka, Huliaipole, Bilotserkivka, and Saltych. The northern part of the Huliaipole Block is composed of tonalite-trondhjemite-granodiorite (TTG) rock association, that hosts the Kosivtsevo greenstone structure. It is composed of metamorphosed rocks of the jaspilite-komatiite-tholeiite association (the Kosivtsevo unit), which corresponds to the Sura Suite of the Konka Series of the Middle Dnieper Domain. The Neoarchean-Paleoproterozoic formations are represented by volcano-sedimentary rocks of the Huliaipole Suite and granitoids of the Dobropillya and Anadol complexes. Granitoids of the Dobropillya complex host numerous pyroxenite, gneiss, and plagioclase granite xenoliths. The U-Pb zircon age of granitoids of the Dobropillya Complex is 2040 Ma and inherited zircon has an age up to 3400 Ma. Small intrusions of two-feldspar granites of the Anadol Complex are widespread in the Ternuvate structure. Their U-Pb monazite age is 2190 Ma. In the central part of the Huliaipole Block, the NW-striking Huliaipole syncline (3.5 × 9 km) occurs. This structure is composed of volcano-sedimentary rocks of the Huliaipole Suite, which unconformably overlie Archean TTG. Felsic and intermediate metavolcanics are confined mainly to ferruginous quartzites of the middle Subsuites. To a limited extent, meta-andesites and felsic metavolcanics are also found in the lower and upper Huliaipole Subsuites. Zircons from meta-andesites and felsic metavolcanics of the Huliaipole Suite are very heterogeneous, indicating their crustal derivation. The U-Pb age of zircon populations from metadacite of the Huliaipole Suite was determined using the LA-ICP-MS method at 3085-2850 and 3700-3360 Ma. In addition, the age of the two crystals exceeded 3800 Ma. According to geological and geochronological data, the Huliaipole Block, 30 × 50 km in size, is composed of rocks and relicts of the Hadean, Archean, and Palaeoproterozoic eons. The oldest nucleoid of the Azov Domain.