A multifunctional material with distinct mechanochromic and piezochromic properties: π-stacking in play
2021
Controlling different types of forces to achieve materials with different emission responses remains challenge. In this work, polymorphic organic crystals with blue (1-B) and green (1-G) emission based on N-(4-(1-cyano-2-phenylvinyl)phenyl)benzamide are prepared. In 1-G, the molecules form continuous π-stacking through π-π interactions, while no π-π interactions are founded in 1-B. When shearing and UV irradiation are applied to 1-G, the emission blue shifts to shorter wavelength region. Experimental investigations show that shearing causes a crystal-to-crystal transition from 1-G to 1-B, while UV irradiation promotes the occurrence of photocycloaddition reaction. The external and internal factors contribute to the destruction of molecular π-stacking. In sharp contrast, under isotropic pressing, 1-G exhibits an obvious red-shifted emission owing to the formation of a tighter packing structure where the π-π interactions are reinforced. This work not only regulates molecular packing and controls emission variations versatilely but also enriches the insights of mechanochromic and multifunctional materials.
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