Nitrogen hydrides in interstellar gas - Herschel/HIFI observations towards G10.6-0.4 (W31C)

The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6−0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N = 1 ← 0, J = 2 ← 1a ndortho-NH2 11,1 ← 00,0. We also observed ortho-NH3 10 ← 00 ,a nd 2 0 ← 10, para-NH3 21 ← 11, and searched unsuccessfully for NH + . All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total column densities over the velocity range 11−54 km s −1 are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen, approximately 6 × 10 −9 ,3 × 10 −9 ,a nd 3× 10 −9 for NH, NH2 ,a nd NH 3, respectively. These abundances are discussed with reference to models of