Asymmetric Catalysis Using Chiral Salen–Metal Complexes: Recent Advances
2019
Chiralsalen–metal complexes are among the most versatile asymmetric catalysts and have found utility in fields ranging from materials chemistry to
organic synthesis. These complexes are capable of inducing
chiralityin products formed from a wide variety of chemical processes, often with close to perfect stereoinduction.
Salen ligandsare tunable for steric as well as electronic properties, and their ability to coordinate a large number of metals gives the derived
chiralsalen–metal complex very broad utility in asymmetric
catalysis. This review primarily summarizes developments in
chiralsalen–metal
catalysisover the last two decades with particular emphasis on those applications of importance in asymmetric synthesis.
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