Multi-reference quantum chemistry protocol for simulating autoionization spectra: Test of ionization continuum models for the neon atom.

In this contribution we present a protocol to evaluate partial and total Augerdecay rates combining the restricted active space self-consistent field electronic structure method for the bound part and numerically obtained continuum orbitals in the single-channel scattering theoryframework. On top of that, the two-step picture is employed to evaluate the partial rates. The performance of the method is exemplified for the prototypical Augerdecay of the neon $1s^{-1}3p$ resonance. Different approximations to obtain the continuum orbitals, the partial rate matrix elements, and the electronic structure of the bound part are tested against theoretical and experimental reference data. It is demonstrated that the partial and total rates are most sensitive to the accuracy of the continuum orbital. For instance, it is necessary to account for the true direct Coulomb potential of the ion for the determination of the continuum wave functions. The Augerenergies, however, can be reproduced quite well already with a rather small active space. Finally, perspectives of the application of the proposed protocol to molecular systems are discussed.