Iron‐Catalyzed Dioxygen‐Driven C—C Bond Formation: Oxidative Dearomatization of 2‐Naphthols with Construction of a Chiral Quaternary Stereocenter.
2013
This reaction proceeds via an asymmetric oxidative dearomatization and coupling to a
nitroalkaneto yield cyclic
enoneswith all-carbon
quaternary
stereocenterswith good enantioselectivity.
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