Dielectric study on mixtures of ionic liquids
2017
Ionic liquidsare promising candidates for electrolytes in energy-storage systems. We demonstrate that mixing two
ionic liquidsallows to precisely tune their physical properties, like the dc conductivity. Moreover, these mixtures enable the gradual modification of the fragility parameter, which is believed to be a measure of the complexity of the
energy landscapein supercooled
liquids. The physical origin of this index is still under debate; therefore, mixing
ionic liquidscan provide further insights. From the chemical point of view, tuning
ionic liquidsvia mixing is an easy and thus an economic way. For this study, we performed detailed investigations by broadband
dielectric spectroscopyand differential scanning calorimetry on two mixing series of
ionic liquids. One series combines an imidazole based with a pyridine based
ionic liquidand the other two different anions in an imidazole based
ionic liquid. The analysis of the glass-transition temperatures and the thorough evaluations of the measured dielectric permittivity and conductivity spectra reveal that the dynamics in mixtures of
ionic liquidsare well defined by the fractions of their parent compounds.
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