Stereoselective synthesis of (±)-urechitol A employing [4+3] cycloaddition
2016
Abstract Urechitol A was synthesized as a
racemateemploying a [4+3]
cycloadditionreaction and a methanol assisted intramolecular epoxide opening as key steps for efficient construction of the core
tricyclicframework. The overall yield was 2.4% over 12 steps.
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