Photoluminescence and energy transfer of Lu3Al5O12:Ce3+, Pr3+ phosphors

Abstract Ce3+ and Pr3+ co−doped Lu3Al5O12 phosphors were synthesized by the sol–gel process, and their crystal structure, photoluminescence (PL) properties, and energy transfer (ET) from the Ce3+ to Pr3+ were studied. The Lu2.94−yAl5O12:0.06Ce3+, yPr3+ phosphors (0.002 ≤ y ≤ 0.008) showed the green−yellow emission from the 2D3/2 → 2F5/2, 7/2 transition of Ce3+ and the red emission at 610 and 637 nm, which were caused by the 1D2→3H4 and 3P0→3H5 transitions of Pr3+, respectively. The optimal concentration of Pr3+ for efficient ET was found to be x = 0.006. The electric quadrupole−quadrupole interaction was responsible for the concentration quenching in the Lu2.94−yAl5O12:0.06Ce3+, yPr3+ phosphors, based on Dexter's theory. The incorporation of Pr3+ for Lu3+ enhanced the red PL intensity in the Lu2.94Al5O12:0.06Ce3+ phosphor.