Linkage isomerism of nitriles in rhodium half-sandwich metallacycles
2008
A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. © 2008 American Chemical Society.
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