Synthesis and Mechanical Properties of sub 5-µm PolyUiO-66 Thin Films on Gold Surfaces.

Metal-organic framework (MOF) thin films currently lack the mechanical stability needed for electronic device applications. Polymer-based metal-organic frameworks (polyMOFs) have been suggested to provide mechanical advantages over MOFs, however, the mechanical properties of polyMOFs have not yet been characterized. In this work, we developed a method to synthesize continuous sub-5 µm polyUiO-66(Zr) films on Au substrates, which allowed us to undertake initial mechanical property investigations.  Comparisons between polyUiO-66 and UiO-66 thin films determined polyUiO-66 thin films exhibit a lower modulus but similar hardness to UiO-66 thin films. The initial mechanical characterization indicates that further development is needed to leverage the mechanical property advantages of polyMOFs over MOFs. Additionally, the demonstration in this work of a continuous surface-supported polyUiO-66 thin film also enables utilization of the emerging class of polyMOF materials in sensors and devices applications.