Second Generation Nanostructured Metal Oxide Matrices to Increase the Thermal Stability of CO and NO2 Sensing Layers Based on Iron(II) Phthalocyanine

An iron(II) phthalocyanine (FePc) complex solubilized by decylamine (DA) and benzylamine(BA) is incorporated into a nanoparticulate metal oxide matrix to develop optical sensor films sensitive to NO 2 and CO. Eleven amine solvents have been tested as N-donor ligands that permit ligand exchange with the gas molecules. We have systematically investigated the suitability of different N-donor ligands, studied the thermal stabilityof the NO 2 - and CO-sensing films at 4, 25, 60, and 80 °C by photometry, and corroborated our findings by using NMR experiments. A satisfactory thermal stabilityof the films has not been obtained for chemically unmodified nanoparticulate metal oxide matrices. We have therefore developed a second generation of nanostructured metal oxide supports that show increased thermal stabilityand adequate sensitivity to NO 2 and CO. These novel nanostructured matrices have been chemically modified using amines, alumina oligomers, and/or anti-gas-fading agents. These components have been integrated into the metal oxide matrices to avoid degradation of the optical films and to preserve their sensitivity.