Construction of 2,3- and 3,4-Functionalized Silacyclopentanes: Synthesis of 6-Aza-2,2-diphenyl-2-silabicyclo[3.1.0]hexane and 6-Aza-3,3-diphenyl-3-silabicyclo[3.1.0]hexane Derivatives.

Abstract The synthesis of five azasilabicyclo[3.1.0]hexanes containing an aziridine function in the α- or the β- position of the silicon atom is described. These bicyclic heterocompounds differ by the various substituents (H, Me, CO2Et, CPh3) on the nitrogen atom.