Facile Fabrication of CeO2-Al2O3 Hollow Sphere with Atomically Dispersed Fe via Spray Pyrolysis.

A facile spray pyrolysis method is introduced to construct the hollow CeO2-Al2O3 spheres with atomically dispersed Fe. Only nitrates and ethanol were involved during the one-step preparation process using the ultrasound spray pyrolysis approach. Detailed explorations demonstrated that differences in the pyrolysis temperature of the precursors and heat transfer are crucial to the formation of the hollow nanostructure. In addition, iron species were in situ atomically dispersed on the as-formed CeO2-Al2O3 hollow spheres via this strategy, which demonstrated promising potential in transferring syn-gas to valuable gasoline products.