High-resolution palaeoenvironmental reconstruction at Zmajevac (Croatia) over the last three glacial/interglacial cycles

Abstract A high-resolution analysis of the Zmajevac loess-palaeosol sequence in East Croatia (Baranja) was performed with the purpose to get new insights into the palaeoenvironmental history during the last three glacial-interglacial cycles. The post-IR infrared stimulated luminescence signal of feldspar, stimulated at 290°C (thereafter pIRIR290) was used to establish a reliable chronological framework and revealed intensive sedimentation during (at least) the last 300 kyr, which was five times interrupted by climate optima resulting in the formation of soils (now palaeosols). The environmental magnetic measurements support the obtained luminescence chronology. Further chronological time control was reached by age modelling based on tie points from variations in frequency dependence of magnetic susceptibility and benthic δ18O variations from the LR04 stack of Lisiecki and Raymo (2005). The grain-size record provided information about the environmental conditions and dust accumulation. Additional palaeoenvironmental implications were provided by room temperature magnetic susceptibility and colourimetric analyses and revealed a continuously lower intensity of pedogenesis, coupled with constantly decreasing temperatures and precipitation from the oxygen isotope stage (OIS) 9 to the end of OIS 3. X-ray diffraction of the clay mineral fraction revealed chlorite, smectite and illitic material as dominant mineral phases. While clay minerals from loess are mostly detrital, smectite from palaeosols is partly of a pedogenic origin. The application of our multi-proxy approach, including relative and numerical dating techniques, provided new insights into a highly resolved terrestrial paleoenvironmental record of Eastern Croatia.