Anchoring of palladium nanoparticles on N-doped mesoporous carbon

Pd nanoparticles deposited on nitrogen-doped mesoporous carbon are promising catalysts for highly selective and effective catalytic hydrogenation reactions. To design and utilize these novel catalysts, it is essential to understand the effect of N-doping on the metal-support interactions. A combined experimental (X-ray photoelectron spectroscopy) and computational (density functional theory study) approach is used to identify preferential adsorption sites and to give detailed explanations of the corresponding metal-support interactions. Pyridinic N atoms turned out to be the preferential adsorption sites for Pd nanoparticles on nitrogen-doped mesoporous carbon, interacting through their lonepairs (LPs) with the Pd atoms via N-LP – Pd d and N-LP – Pd s as well as Pd d – * charge transfer, which leads to a change in the Pd oxidation state. Our results evidence the existence of bi-functional palladium nanoparticles containing Pd0 and Pd2+ centers.