Characterization of cetylpyridinium bromide-modified montmorillonite incorporated cellulose acetate nanocomposite films

An organoclay(MMT–CPB) based on montmorillonite (MMT) and cetylpyridiniumbromide (CPB) was synthesized by a cationic interchange process. The presence of CPB into the clay structure was evidenced by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric analysis (TGA). This organoclaywas then used to prepare cellulose acetate(CA) nanocomposite films with different content of this nanofiller (2.5–7.5 wt%) through a casting technique. All nanocomposites were characterized by XRD, FTIR, differential scanning calorimetry, TGA, optical and mechanical analyses. So, nanocomposites were characterized by the intercalation of CA into the clay structure. Organoclaycontent did not affect the glass transition (T g) and melting temperature (T m) of CA; however, thermal stability of CA was slightly improved with the presence of the organoclay. Therefore, optical and mechanical properties were significantly affected with the increase of the organoclaycontent into the CA. On the other hand, electrical conductivity (EC) measurement was performed to evaluate the release of cetylpyridiniumfrom the CA nanocomposites to an aqueous medium. An important increase of the EC over time was observed. Therefore, the EC values were dependent on the content of MMT–CPB in the CA nanocomposites. However, a likely degradation of cellulose acetatein the aqueous medium affected the surfactant quantification.