Polymeric Terbium(III) Squarate Hydrate as a Luminescent Magnet

Polymeric terbium(III) squarate hydrate [{Tb2(C4O4)3(H2O)8}n] was prepared from TbCl3 or Tb2O3 and squaric acid. The crystal structure was determined in a monoclinic Pc space group, and the whole molecular arrangement gives a sandwiched two-dimensional structure. The coordination polyhedra are described as a square antiprism. The solid complex emits green light under UV irradiation at room temperature with the quantum yield of 25%. Although Tb3+ is a non-Kramers ion, the alternating-current magnetic susceptibility showed frequency dependence in a 2000-Oe DC field, and the effective energy barrier for magnetization reorientation was 33(2) K. Thus, [{Tb2(C4O4)3(H2O)8}n] displayed functions of a potential luminescent magnet.